Ferro- and antiferromagnetic coupling in a chlorido-bridged, tetranuclear Cu(ii) complex

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Ferro- and antiferromagnetic coupling in a chlorido-bridged, tetranuclear Cu(II) complex.

A bispidine-like ligand involving four pyridine-N and three aliphatic-N donor atoms forms a bimetallic species with CuCl2 in which all seven N-donors are bound and which aggregates in the crystal through double chloride-bridging to give a tetranuclear unit. The magnetism of this solid can be interpreted in terms of a relatively weak antiferromagnetic coupling between the two Cu(ii) centres of t...

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ژورنال

عنوان ژورنال: Dalton Trans.

سال: 2014

ISSN: 1477-9226,1477-9234

DOI: 10.1039/c4dt00305e